More on Vinyl Cholride in Tampa Bay Groundwater

More news stories on the chemical plume spreading in the Tampa Area.  This follows my previous post about Vinyl Chloride in the Groundwater.

Joe Dindino said he has lived on 10th Avenue North for 30 years, and had no idea that chemicals such as dioxane, TCE and vinyl chloride were contaminating the ground in his neighborhood until a news reporter told him.

He wants to know why Raytheon didn't tell residents when its tests showed the plume was moving off the plant's property and under homes.


Source:  TBO.com Tampa Bay Online: Plume has residents pondering its impact.

Toxic Plume in Florida threatens Neighborhood

From the Tampa Bay Online and story about how a toxic plume is threatening the water supply with cancer causing chemicals such as TCE and Vinyl Chloride.

A toxic plume of industrial waste discovered by workers building the Pinellas Trail 17 years ago is now coursing through groundwater under Abel's Azalea neighborhood, beneath parks, playgrounds and hundreds of homes, according to samples drawn from test wells.


Source:  TBO Online

Safety Data fo Vinyl Chloride

General

Synonyms: vinyl chloride monomer, monochloroethylene, ethylene monochloride, monochloroethene, VC, VCM, chloroethene, chloroethylene
Molecular formula: C2H3Cl
CAS No: 75-01-4
EINECS No: 200-831-0
Annex I Index No: 602-023-00-7

Physical data

Appearance: colourless gas
Melting point: -153.7 C
Boiling point: -13.9 C
Vapour density: 2.2 (air = 1)
Vapour pressure: 2580 mm Hg at 20 C
Density (g cm-3): 0.9106
Flash point: -61 C (closed cup)
Explosion limits:
Autoignition temperature:
Water solubility: 0.11 g 100 cm-3 at 25 C
Critical temperature: 156.5 C


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Worldwide Attention to PVC

From the Africa Science News a call to recycle and reduce PVC usage.

Polyvinyl chloride (PVC) is used plumbing pipes and guttering, shower curtains, window frames and flooring. Polypropylene (PP) is used in food containers, appliances and car fenders (bumpers).

There has been growing concern on not only the environmental degradation effects through the use of all these kinds of plastics but also their negative health effect to consumers particularly when used in food packaging. Many organizations are raising an alarm on the same issue.

For instance, PVC contains numerous toxic chemicals called adipates (plasticizers) which make it more flexible thus enabling it to be used for packaging food a and liquids, in plumbing and building materials and even in cosmetics.

It has been found that these chemicals leach out when the PVC comes into contact with food. The World Health Organization (WHO)’s International Agency for Research on Cancer (IARC) has recognized the chemicals used to make PVC, vinyl chloride, as a known human carcinogen.

Also some compounds that leach out from Styrofoam food containers interfere with the body hormonal functions. It is a possible human carcinogen.

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Two Vinyl Chloride Links today

The first is from USAToday.com:

Toy Safety Steps back into National SpotLight:  Toy safety emerged as a major issue last year after manufacturers recalled millions of children's products because of lead paint, magnets and other health hazards. Heightened concerns about toys helped win approval of a "toxic toy" law in California, which last October became the first state to ban phthalates, softening agents found in vinyl products that have been linked to reproductive problems in many animal tests and a few human studies.


And:

Baby goes Green:  Organic Toys and Clothes a rising trend: [F}ollowing recent scares about dangerous chemicals in toys and other children’s products, more parents are following Cannon’s early example and searching out natural and organic clothing and accessories for their babies.

...

Chemical concerns

Iplay’s Cannon said that the U.S. is still catching up to Japan and Europe, which have much stricter standards on the chemicals that can be used in baby products.

The European Union has banned some chemicals that are used to soften the polyvinyl chloride — vinyl — used to make bibs and other items. The typical culprit is lead, already identified as a carcinogen by the Environmental Protection Agency. Wal-Mart, Target and Sears have started programs to get rid of some of these products under pre-ssure from environmentalists who worry children can ingest these chemicals by chewing on vinyl products.

Toxic exposure and autoimmune disease

I was skimming my Google News alerts today and came upon this blog post.  Workers at Risk

The blog is by

Here's the post.

There is mounting evidence from occupational studies of the link between environmental toxins and autoimmune disease. In 2007, scientists from the National Institutes of Health announced a new report on exposures to chemicals and death from autoimmune disease. After studying 300,000 death certificates in 26 states over a 14-year period, researchers found that people who worked with pesticides, textiles, hand painting, solvents (such as TCE), benzene, asbestos, and other compounds were significantly more likely to die from an autoimmune disease than people who were not exposed. Other recent studies likewise show links between working with pesticides, TCE solvents, silica, asbestos, PCBs and vinyl chloride and a greater likelihood of developing autoimmune disease

Yes there is PVC in your Shower Curtain

From over at the Seattle Times an article about greening your bathroom has a section covering PVCs in plastic shower curtains.

Shower showdown

Pop in the shower first, and take a look at your shower curtain. Yikes! If it has mold or grunge (we've all been there), you need to clean it or replace it. Several cleaning-tip Web sites recommend tossing your shower curtain in the washing machine with a couple towels, using detergent and a little bleach. But don't put it in the dryer; let it drip dry.

Most shower curtains are made of polyvinyl chloride (PVC), a plastic that can emit toxics into the environment, especially during production. When you need a new shower curtain, consider a greener, chlorine-free material called polyethylene vinyl acetate (PEVA or EVA).

As part of a toxics-reduction effort, Target currently offers shower curtains and liners made from EVA as well as cloth and is working to achieve a nearly 90 percent non-PVC level in its own brands by spring, according to Target spokesman Joshua Thomas.

Vinyl Chloride Lawsuit: McCollum Lake

We are involved with individual lawsuits, mostly concerning industrial exposure.  Here is an article covering a lawsuit claiming that liver cancer (probably angiosarcoma) was caused by environmental exposure to vinyl chloride.

The family of a longtime McHenry resident has become the latest to sue two Ringwood manufacturers for allegedly causing cancer by polluting air and groundwater.

Next of kin of the late Edward Linnane filed the lawsuit late last month in Pennsylvania state court accusing Rohm and Haas and Modine Manufacturing Co. of causing the liver cancer that killed Linnane, 74, in 1993. The lawsuit is the 23rd to be filed on behalf of current or former McCullom Lake area residents since April 2006.

Source:  Northwest Herald

It Causes cancer in the workplace. So what about Toys?

Now people are worried about toys too.  PVC Poly vinyl chloride is in many toys and plastic bottles in the home.  Consumer groups are pushing to have these toys removed from the market.  That idea is gaining traction.  Already the European Union has banned the chemical and California moving toward that too. 

After recalling millions of toys to protect consumers from lead paint, toy makers face growing pressure over another material, a plastic found in myriad playthings, from balls to dolls.

The Toy Industry Association, the manufacturers' trade group, says polyvinyl chloride, or PVC, in toys poses no safety risks. Still, retail giants Wal-Mart Stores Inc., Target Corp. and Sears Holdings Corp. have started programs to get rid of some of the toys and other products that contain PVC, bowing to pressure from environmental activists concerned that children who chew on PVC could ingest dangerous chemicals. Some of these chemicals have been banned in the European Union and will also be illegal in California under a law effective next year.

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Vinyl Chloride in the Home

PVC is a dangerous substance.  It is dangerous in the factory when it is made and it is dangerous through it's entire life cycle to the trash.  Watch this Video about vinyl chloride.

To learn more go to www.pvcfree.org


Vinyl Chloride in the Water.

It does not take much to contaminate a well or an aquifer.  We have seen this with other chemicals such as MtBE and benzene.  In this article you can see that people had used bottled water for years, but the regulators only recently seemed to catch up.

It is amazing to me to see how much we all really do not know about how these chemicals really are affecting water supplies around the world.

Earlier this month, Delaware's Department of Natural Resources and Environmental Control notified owners of four properties near U.S. 13 and Wrangle Hill Road that they would be eligible for free United Water Delaware connections. The offer followed the unexplained appearance of a cancer-causing chemical, ethylene dichloride, in a well near the St. Georges Getty service station just north of the car dealership.

Officials had assured area residents for more than two decades that pollution from the site of the old Stauffer Chemical Co. toxic-waste landfills to the north was under control. That they were wrong underscores how little is known about how toxic chemicals make their way through complex geological formations into drinking-water supplies.

If you don't think a little of this stuff in your drinking water matters, then check out these statistics:

Stauffer and its successor, Formosa Plastics, both were named as responsible parties for the chemical contamination found in groundwater in the early 1980s near what is now Formosa's plant. The pollutants, which leached from unlined pits and storage lagoons, included vinyl chloride, ethylene dichloride and trichloroethylene, solvents or chemicals used in plastics manufacturing.

When found in drinking water even in trace amounts, ethylene dichloride is considered nearly three times more potent than benzene, a known carcinogen present in materials ranging from gasoline to cigarettes and automobile exhaust, according to calculations released by the nonprofit group Environmental Defense.

Vinyl chloride, a common plastic, can pose a cancer risk nearly five times higher than benzene when dissolved in water.

Delaware Online

Common Household Pollutants

While we only pursue cases involving more intense exposure here is an interesting link from a website focusing more on household  toxins:

Vinyl chloride is the source of “new car smell”: The plastic interior of a new car off-gasses this known carcinogen. Water sitting in PVC pipes overnight may be steeping into a toxic tea. Very large exposures can lead to “vinyl chloride disease,” which causes severe liver damage and ballooning of the fingertips.

Source:  Kitchen Table Medicine

It's in Beauty Salons too

Careful.  These products (vinyl Chloride) are not just in industrial settings.  Vinyl Chloride was once very common in beauty salons.  It still shows up there...

One of the most common types of synthetic hair is made from fibers known as modacrylics. These consist of a long chain synthetic polymers composed of less than 85% but at least 35% by weight of acrylonitrile units. (-CH2CH[CN]-)x. (I’m sorry, but the Left Brain made me put in the chemical structure. I apologize in advance for the geekiness.) Modacrylics can also include mixtures of acrylonitrile and other materials, such as vinyl chloride, vinylidene chloride or vinyl bromide. (Yawn, enough organic chemistry already!)


Source:  The Beauty Brains

Australia Toxic Dump to close

There is concern around the globe about exposure to Vinyl Chloride.  Here is an article from Australia about a toxic dump closing.  One of the big concerns in that dump appears to be an ongoing vinyl chloride leak.  A leak that was leaching into water supplies.

THE controversial Tullamarine toxic dump was set to close yesterday — and may never reopen.

The dump will remain closed while the Environment Protection Authority assesses the site to determine whether it has reached its capacity.

Even if the site does reopen it will close its gates permanently no later than August this year — more than a year earlier than the previous September 2009 deadline.

Members of the Terminate Tullamarine Toxic Dump Action Group, who have led a hard-fought battle to close the dump for more than two years, declared victory last week.

“If we hadn’t been vigilant ... who knows what they would have been capable of,” TTTDAG spokeswoman Kaylene Wilson said.

“The fact that we’re here, making noise, keeping them accountable to everything they’re doing — I think it’s just all got a bit too hard for them.”

The closure of the Western Ave site came after Transpacific Cleanaway told the EPA the landfill would reach its capacity much earlier than expected.

Last week Star reported the EPA had ordered Cleanaway to relocate 15,000 cubic metres of contaminated soil to a designated landfill area.


Source:  Star News